Recent applications of ring-rearrangement metathesis in organic synthesis
Sambasivarao Kotha, Milind Meshram, Priti Khedkar, Shaibal Banerjee, Deepak Deodhar
TL;DR
This review discusses recent uses of ring-rearrangement metathesis in making complex organic molecules efficiently.
Contribution
The novelty lies in summarizing recent advancements in ring-rearrangement metathesis for streamlined organic synthesis.
Findings
RRM enables multi-bond formation in a single step, improving atom economy.
The review highlights RRM's ability to synthesize complex frameworks not easily achieved by traditional methods.
Applications from 2008–2014 demonstrate RRM's growing importance in organic synthesis.
Abstract
Ring-rearrangement metathesis (RRM) involves multiple metathesis processes such as ring-opening metathesis (ROM)/ring-closing metathesis (RCM) in a one-pot operation to generate complex targets. RRM delivers complex frameworks that are difficult to assemble by conventional methods. The noteworthy point about this type of protocol is multi-bond formation and it is an atom economic process. In this review, we have covered literature that appeared during the last seven years (2008–2014).
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Taxonomy
TopicsMetal-Organic Frameworks: Synthesis and Applications · Catalytic Processes in Materials Science