Charge-Induced Polarization in Dielectric Particle Systems: A Geometry-Dependent Effect
Eric B. Lindgren

TL;DR
This paper explores how the shape and size of dielectric particles affect electrostatic interactions, leading to unexpected behaviors like like-charge attraction.
Contribution
The study introduces a geometry-based cutoff method to efficiently model many-body polarization effects in dielectric particle systems.
Findings
Asymmetries in particle size or charge can cause like-charge attraction and complex force balances.
A boundary-integral framework shows induced surface charges propagate through iterative cascades.
Geometry-based cutoffs enable efficient computation of long-range and near-field interactions.
Abstract
Electrostatic interactions in systems composed of finite-sized dielectric materials extend well beyond simple point-charge approximations, particularly when many-body polarization effects become significant. This study shows that asymmetries in the size or net charge of spherical particles can trigger nontrivial phenomena, including like-charge attraction and intricate force balances involving neutral species. Through a rigorous boundary-integral framework, it is substantiated that induced surface charges propagate through iterative cascades, reflecting the full many-body, nonadditive character of polarization. Significantly, a geometry-based cutoff is adopted to discriminate whether long-range interactions can be approximated by monopoles, thereby retaining near-field multipole couplings without forfeiting computational efficiency. This approach provides significant computational gains…
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Taxonomy
TopicsElectrostatics and Colloid Interactions · Material Dynamics and Properties · Iron oxide chemistry and applications
