# Charge-Induced Polarization in Dielectric Particle Systems: A Geometry-Dependent Effect

**Authors:** Eric B. Lindgren

PMC · DOI: 10.1021/acs.jctc.5c00544 · 2025-06-12

## TL;DR

This paper explores how the shape and size of dielectric particles affect electrostatic interactions, leading to unexpected behaviors like like-charge attraction.

## Contribution

The study introduces a geometry-based cutoff method to efficiently model many-body polarization effects in dielectric particle systems.

## Key findings

- Asymmetries in particle size or charge can cause like-charge attraction and complex force balances.
- A boundary-integral framework shows induced surface charges propagate through iterative cascades.
- Geometry-based cutoffs enable efficient computation of long-range and near-field interactions.

## Abstract

Electrostatic interactions
in systems composed of finite-sized
dielectric materials extend well beyond simple point-charge approximations,
particularly when many-body polarization effects become significant.
This study shows that asymmetries in the size or net charge of spherical
particles can trigger nontrivial phenomena, including like-charge
attraction and intricate force balances involving neutral species.
Through a rigorous boundary-integral framework, it is substantiated
that induced surface charges propagate through iterative cascades,
reflecting the full many-body, nonadditive character of polarization.
Significantly, a geometry-based cutoff is adopted to discriminate
whether long-range interactions can be approximated by monopoles,
thereby retaining near-field multipole couplings without forfeiting
computational efficiency. This approach provides significant computational
gains without compromising the rigor of many-body treatment, underscoring
the critical interplay between geometric factorsspecifically,
particle size (and its associated curvature) and interparticle separationin
determining local field intensities, which often exceed conventional
Coulombic predictions. The findings can illuminate pathways for understanding
and designing advanced materials and self-assembled architectures
in which dielectric polarization governs or contributes to emergent
behavior.

## Full-text entities

- **Chemicals:** Omega2 (-)

## Figures

24 figures with captions in the complete paper: https://tomesphere.com/paper/PMC12199467/full.md

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Source: https://tomesphere.com/paper/PMC12199467