First astrophysical detection of the helium hydride ion (HeH$^+$)
Rolf G\"usten, Helmut Wiesemeyer, David Neufeld, Karl M. Menten, Urs, U. Graf, Karl Jacobs, Bernd Klein, Oliver Ricken, Christophe Risacher,, J\"urgen Stutzki

TL;DR
This paper reports the first astrophysical detection of the helium hydride ion (HeH$^+$), a molecule believed to be the first formed in the universe, using the SOFIA telescope's spectrometer.
Contribution
The study provides the first confirmed detection of HeH$^+$ in space, confirming its role in early universe chemistry and advancing observational astrophysics.
Findings
Detection of HeH$^+$ in planetary nebula NGC7027
Validation of theoretical models of early universe chemistry
Advancement in observational techniques for interstellar molecules
Abstract
During the dawn of chemistry when the temperature of the young Universe had fallen below 4000 K, the ions of the light elements produced in Big Bang nucleosynthesis recombined in reverse order of their ionization potential. With its higher ionization potentials, He (54.5 eV) and He (24.6 eV) combined first with free electrons to form the first neutral atom, prior to the recombination of hydrogen (13.6 eV). At that time, in this metal-free and low-density environment, neutral helium atoms formed the Universe's first molecular bond in the helium hydride ion HeH, by radiative association with protons (He + H HeH + h). As recombination progressed, the destruction of HeH (HeH + H He + H) created a first path to the formation of molecular hydrogen, marking the beginning of the Molecular Age. Despite its unquestioned…
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