# First astrophysical detection of the helium hydride ion (HeH$^+$)

## TL;DR

This paper reports the first astrophysical detection of the helium hydride ion (HeH$^+$), a molecule believed to be the first formed in the universe, using the SOFIA telescope's spectrometer.

## Contribution

The study provides the first confirmed detection of HeH$^+$ in space, confirming its role in early universe chemistry and advancing observational astrophysics.

## Key findings

- Detection of HeH$^+$ in planetary nebula NGC7027
- Validation of theoretical models of early universe chemistry
- Advancement in observational techniques for interstellar molecules

## Abstract

During the dawn of chemistry when the temperature of the young Universe had fallen below $\sim$4000 K, the ions of the light elements produced in Big Bang nucleosynthesis recombined in reverse order of their ionization potential. With its higher ionization potentials, He$^{++}$ (54.5 eV) and He$^+$ (24.6 eV) combined first with free electrons to form the first neutral atom, prior to the recombination of hydrogen (13.6 eV). At that time, in this metal-free and low-density environment, neutral helium atoms formed the Universe's first molecular bond in the helium hydride ion HeH$^+$, by radiative association with protons (He + H$^+$ $\rightarrow$ HeH$^+$ + h$\nu$). As recombination progressed, the destruction of HeH$^+$ (HeH$^+$ + H $\rightarrow$ He + H$_2^+$) created a first path to the formation of molecular hydrogen, marking the beginning of the Molecular Age. Despite its unquestioned importance for the evolution of the early Universe, the HeH$^+$ molecule has so far escaped unequivocal detection in interstellar space. In the laboratory, the ion was discovered as long ago as 1925, but only in the late seventies was the possibility that HeH$^+$ might exist in local astrophysical plasmas discussed. In particular, the conditions in planetary nebulae were shown to be suitable for the production of potentially detectable HeH$^+$ column densities: the hard radiation field from the central hot white dwarf creates overlapping Str\"omgren spheres, where HeH$^+$ is predicted to form, primarily by radiative association of He$^+$ and H. With the GREAT spectrometer onboard SOFIA, the HeH$^+$ rotational ground-state transition at $\lambda$149.1 $\mu$m is now accessible. We report here its detection towards the planetary nebula NGC7027.

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Source: https://tomesphere.com/paper/1904.09581