On the connection between the radial momentum operator and the Hamiltonian in n dimensions
Gil Paz

TL;DR
This paper investigates the relationship between the radial momentum operator and the Hamiltonian in n-dimensional quantum mechanics, revealing an extra term needed for dimensions other than one or three.
Contribution
It demonstrates that the standard Hamiltonian-radial momentum connection requires an additional term in dimensions other than one or three.
Findings
The known Hamiltonian-radial momentum relation holds only in 1D and 3D.
An extra term proportional to 44(n-1)(n-3)/2m4r^{2}44 is necessary in general.
The extra term vanishes in 1D and 3D, confirming the standard relation.
Abstract
The radial momentum operator in quantum mechanics is usually obtained through canonical quantization of the (symmetrical form of the) classical radial momentum. We show that the well known connection between the Hamiltonian of a free particle and the radial momentum operator \hat{L}^2}/2mr^{2} is true only in one or three dimensions. In general, an extra term of the form has to be added to the Hamiltonian.
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Taxonomy
TopicsQuantum and Classical Electrodynamics · Quantum chaos and dynamical systems · Advanced Physical and Chemical Molecular Interactions
