Charge ordering and long-range interactions in layered transition metal oxides: a quasiclassical continuum study

TL;DR

This study investigates charge ordering in layered transition metal oxides using a novel quasiclassical continuum approach, revealing multiple phases and complex dynamics influenced by long-range interactions and impurities.

Contribution

Develops a new numerical method to analyze charge ordering at finite densities in large systems, incorporating long-range Coulomb interactions in a quasiclassical framework.

Findings

Identifies four distinct charge phases: Wigner crystal, stripes, grid, and glassy-clumped.

Shows impurities suppress stripe order but allow finite segments.

Reveals multiscale dynamics similar to glassy systems.

Abstract

The competition between long-range and short-range interactions among holes moving in an antiferromagnet (AF), is studied within a model derived from the spin density wave picture of layered transition metal oxides. A novel numerical approach is developed which allows one to solve the problem at finite hole densities in very large systems (of order hundreds of lattice spacings), albeit in a quasiclassical limit, and to correctly incorporate the long-range part of the Coulomb interaction. The focus is on the problem of charge ordering and the charge phase diagram: at low temperatures four different phases are found, depending on the strength of the magnetic (dipolar) interaction generated by the spin-wave exchange, and the density of holes. The four phases are the Wigner crystal, diagonal stripes, a grid phase (horizontal-vertical stripe loops) and a glassy-clumped phase. In the presence of both in-plane and out-of-plane charged impurities the stripe ordering is suppressed, although finite stripe segments persist. At finite temperatures multiscale (intermittency) dynamics is found, reminiscent of that in glasses. The dynamics of stripe melting and its implications for experiments is discussed.