Instabilities in crystal growth by atomic or molecular beams

TL;DR

This review discusses various instabilities in crystal growth via atomic or molecular beams, focusing on kinetic and thermodynamic causes, their mechanisms, and experimental observations, especially in Molecular Beam Epitaxy.

Contribution

It provides a comprehensive analysis of growth instabilities, including geometric, kinetic, and thermodynamic factors, with detailed discussion on Ehrlich-Schwoebel effects and lattice mismatch phenomena.

Findings

Kinetic instabilities lead to mound formation and coarsening.

Thermodynamic instabilities include misfit dislocations and surface deformations.

Theories and experiments show qualitative agreement, but some questions remain.

Abstract

The planar front of a growing a crystal is often destroyed by instabilities. In the case of growth from a condensed phase, the most frequent ones are diffusion instabilities, which will be but briefly discussed in simple terms in chapter II. The present review is mainly devoted to instabilities which arise in ballistic growth, especially Molecular Beam Epitaxy (MBE). The reasons of the instabilities can be geometric (shadowing effect), but they are mostly kinetic or thermodynamic. The kinetic instabilities which will be studied in detail in chapters IV and V result from the fact that adatoms diffusing on a surface do not easily cross steps (Ehrlich-Schwoebel or ES effect). When the growth front is a high symmetry surface, the ES effect produces mounds which often coarsen in time according to power laws. When the growth front is a stepped surface, the ES effect initially produces a meandering of the steps, which eventually may also give rise to mounds. Kinetic instabilities can usually be avoided by raising the temperature, but this favours thermodynamic instabilities. Concerning these ones, the attention will be focussed on the instabilities resulting from slightly different lattice constants of the substrate and the adsorbate. They can take the following forms. i) Formation of misfit dislocations (chapter VIII). ii) Formation of isolated epitaxial clusters which, at least in their earliest form, are `coherent' with the substrate, i.e. dislocation-free (chapter X). iii) Wavy deformation of the surface, which is presumably the incipient stage of (ii) (chapter IX). The theories and the experiments are critically reviewed and their comparison is qualitatively satisfactory although some important questions have not yet received a complete answer.