Effects of Defects on Friction for a Xe Film Sliding on Ag(111)

TL;DR

This study investigates how step and point defects on a silver substrate affect the frictional behavior of a xenon monolayer film sliding over it, using molecular dynamics simulations and perturbation theory.

Contribution

It provides new insights into defect-induced frictional effects and compares simulation results with theoretical predictions for real surface conditions.

Findings

Friction force depends on defect type and sliding direction.

Pinning occurs below a critical force, influenced by defect presence.

Simulations align with perturbation theory, aiding understanding of real surface behavior.

Abstract

The effects of a step defect and a random array of point defects (such as vacancies or substitutional impurities) on the force of friction acting on a xenon monolayer film as it slides on a silver (111) substrate are studied by molecular dynamic simulations and compared with the results of lowest order perturbation theory in the substrate corrugation potential. For the case of a step, the magnitude and velocity dependence of the friction force are strongly dependent on the direction of sliding respect to the step and the corrugation strength. When the applied force F is perpendicular to the step, the film is pinned forF less than a critical force Fc. Motion of the film along the step, however, is not pinned. Fluctuations in the sliding velocity in time provide evidence of both stick-slip motion and thermally activated creep. Simulations done with a substrate containing a 5 percent concentration of random point defects for various directions of the applied force show that the film is pinned for the force below a critical value. The critical force, however, is still much lower than the effective inertial force exerted on the film by the oscillations of the substrate in experiments done with a quartz crystal microbalance (QCM). Lowest order perturbation theory in the substrate potential is shown to give results consistent with the simulations, and it is used to give a physical picture of what could be expected for real surfaces which contain many defects.