Boundary Effects in Chiral Polymer Hexatics
Randall D. Kamien, Alex J. Levine

TL;DR
This paper explores how boundary effects can induce a three-dimensional N+6 phase in chiral polymer hexatics, potentially explaining recent experimental observations of polymer hexatic phases.
Contribution
It demonstrates that boundary effects can lock chiral hexatic phases into an N+6 phase, offering a new interpretation of polymer hexatic behavior.
Findings
Boundary effects can induce a three-dimensional N+6 phase in chiral hexatics.
Numerical estimates suggest polymer hexatic may be this boundary-locked phase.
The study provides a new perspective on the structure of polymer hexatics.
Abstract
Boundary effects in liquid-crystalline phases can be large due to long-ranged orientational correlations. We show that the chiral hexatic phase can be locked into an apparent three-dimensional N+6 phase via such effects. Simple numerical estimates suggest that the recently discovered "polymer hexatic" may actually be this locked phase.
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Taxonomy
TopicsProtein Structure and Dynamics · Liquid Crystal Research Advancements · Molecular spectroscopy and chirality
