A Variational Approach to the Localization Transition of Heteropolymers at Interfaces

TL;DR

This paper investigates the localization transition of heteropolymer chains at interfaces using a variational replica approach, revealing a temperature-driven transition and instability of replica symmetry.

Contribution

It introduces a Gaussian variational method in replica space to analyze the localization transition of heteropolymers at interfaces, including replica symmetry breaking.

Findings

Transition temperature diverges near neutrality

Chain localizes at low temperatures

Replica symmetry is unstable

Abstract

A chain with random hydrophobic-hydrophilic charges is studied in the presence of an interface separating a polar from a non polar solvent. Within a Gaussian variational approach in replica space, a transition is found, from a high temperature region, where the chain is delocalized, to a low temperature region, where the chain is localized at the interface. The transition temperature diverges as the neutrality of the chain is approached. Our results are in agreement with an Imry-Ma type argument by Garel et al. The problem of replica symmetry breaking is also addressed, and the replica-symmetric solution is found to be unstable.