Effective Hamiltonian with holomorphic variables
A.Cuccoli, V.Tognetti, R.Giachetti, R.Maciocco, R.Vaia

TL;DR
This paper reformulates the pure-quantum self-consistent harmonic approximation using holomorphic variables, enabling direct analysis of Hamiltonians expressed with bosonic creation and annihilation operators.
Contribution
It introduces a holomorphic variable approach to PQSCHA, broadening its applicability to general bosonic Hamiltonians.
Findings
Allows direct treatment of bosonic Hamiltonians
Provides a new holomorphic path integral formulation
Enhances the analytical tools for quantum systems
Abstract
The pure-quantum self-consistent harmonic approximation (PQSCHA) permits to study a quantum system by means of an effective classical Hamiltonian. In this work the PQSCHA is reformulated in terms of the holomorphic variables connected to a set of bosonic operators. The holomorphic formulation, based on the olomorphic path integral for the Weyl symbol of the density matrix, makes it possible to directly approach general Hamiltonians given in terms of bosonic creation and annihilation operators.
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Taxonomy
TopicsAdvanced Chemical Physics Studies · Spectroscopy and Quantum Chemical Studies · Advanced Physical and Chemical Molecular Interactions
