Ferromagnetic Mixed-Valence and Kondo-Lattice State in TmTe at High Pressure

TL;DR

This study investigates the magnetic and electronic phase transitions in TmTe under high pressure, revealing a transition from ferromagnetic to potential quantum critical behavior linked to mixed-valence and Kondo effects.

Contribution

It provides experimental evidence of pressure-induced ferromagnetism and potential quantum criticality in TmTe, highlighting the interplay of mixed-valence states and Kondo fluctuations.

Findings

Semiconductor-to-metal transition at 2 GPa with ferromagnetic order

High Curie temperature of 14 K near transition

Possible quantum critical point around 6 GPa

Abstract

Neutron diffraction experiments on TmTe at pressures up to 7 GPa are reported. The semiconductor-to-metal transition occurring at 2 GPa in this compound is accompanied by the appearance of strong ferromagnetic exchange interactions producing a Curie temperature as high as 14 K. This behavior is characteristic for the incipient mixed-valence regime just above the transition pressure and traced back to the release of a small concentration of free charge carriers in the material. The steep decrease of both the Curie temperature and ordered magnetic moment occurring at higher pressures emphasizes the role of Kondo fluctuations, and raises the interesting possibility that a quantum critical transition to a non-magnetic ground state of mixed-valence Tm might take place around 6 GPa.