Plasmons in simple-metal slabs: a semiclassical approach

TL;DR

This paper develops a semiclassical approach to analyze plasmon modes in simple-metal slabs, calculating dispersion relations and density fluctuations, and comparing results with previous RPA and TDLDA methods.

Contribution

It introduces a variational semiclassical method for plasmon analysis in slabs, incorporating exchange-correlation effects and slab width dependence.

Findings

Identification of two multipole plasmon modes below plasma frequency

Qualitative differences from local optics calculations in spectra

Dependence of plasmon characteristics on slab width and surface diffuseness

Abstract

Collective excitations in simple metal systems can be described successfully in terms of a local one-body excitation operator Q, due to the long range nature of the coulomb interaction. For the plasmon modes of a simple-metal slab, momentum expansions of Q are calculated using a variational procedure, equivalent to a restricted RPA calculation. The dispersion relation and the density fluctuation for each mode are found in the sudden approximation using the proper Q operator and the RPA sum-rule formalism. The contribution of the exchange and correlation energy is estimated using a local density functional. The positive background is described within a jellium model while the ground-state electronic density is approximated by a double step profile. The density fluctuation of the plasmon modes above the plasma frequency form standing waves across the slab. The spectra below the plasma frequency is qualitatively different to that of local optics calculations, due to the appearance of two multipole plasmon modes that shift down the origin of the $\omega_{+}$ plasmon. The dependence of the results on the width of the slab, the density of the simple-metal and the surface diffuseness is discussed. Throughout, we compare our results with previous RPA and TDLDA calculations.