Quantum Relaxation of Magnetisation in Magnetic Particles

TL;DR

This paper investigates quantum relaxation mechanisms of magnetization in small magnetic particles, highlighting the significant role of nuclear spins and phonons, with implications for magnetic materials and device technology.

Contribution

It provides a comprehensive analysis of quantum relaxation processes in magnetic particles, incorporating nuclear spin and phonon couplings, and reveals temperature-dependent unblocking phenomena.

Findings

Microscopic particles on conducting substrates have magnetization frozen over millennia at low temperatures.

Nuclear spins significantly enhance relaxation in insulating systems.

Relaxation dynamics can be logarithmic, exponential, or power-law depending on temperature.

Abstract

At temperatures below the magnetic anisotropy energy, monodomain magnetic systems (small particles, nanomagnetic devices, etc.) must relax quantum mechanically. This quantum relaxation must be mediated by the coupling to both nuclear spins and phonons (and electrons if either particle or substrate is conducting. We analyze the effect of each of these couplings, and then combine them. Conducting systems can be modelled by a "giant Kondo" Hamiltonian, with nuclear spins added in as well. At low temperatures, even microscopic particles on a conducting substrate (containing only $10-50$ spins) will have their magnetisation frozen over millenia by a combination of electronic dissipation and the "degeneracy blocking" caused by nuclear spins. Raising the temperature leads to a sudden unblocking of the spin dynamics at a well defined temperature. Insulating systems are quite different. The relaxation is strongly enhanced by the coupling to nuclear spins. At short times the magnetisation of an ensemble of particles relaxes logarithmically in time, after an initial very fast decay; this relaxation proceeds entirely via the nuclear spins. At longer times phonons take over, but the decay rate is still governed by the temperature-dependent nuclear bias field acting on the particles - decay may be exponential or power-law depending on the temperature. The most surprising feature of the results is the pivotal role played by the nuclear spins. The results are relevant to any experiments on magnetic particles in which interparticle dipolar interactions are unimportant. They are also relevant to future magnetic device technology.