Zeros of the partition function for a continuum system at first order transitions
Koo-Chul Lee

TL;DR
This paper extends the circle theorem to continuum systems, calculates exact zeros of the partition function for finite systems with asymmetric Gaussian peaks, and characterizes the zeros' locus and density at first order transitions.
Contribution
It generalizes the circle theorem to continuum systems and provides explicit formulas for the zeros' distribution at first order phase transitions.
Findings
Derived the locus of zeros as $r = e^{(rac{ riangle c}{2l}) heta^2}$
Calculated the angular density of zeros as $2\pi g( heta)=l(1+rac{3}{2}(rac{ riangle c}{l})^2 heta^2)$
Extended the understanding of zeros distribution in complex plane for phase transition analysis.
Abstract
We extend the circle theorem on the zeros of the partition function to a continuum system. We also calculate the exact zeros of the partition function for a finite system where the probability distribution for the order parameter is given by two asymmetric Gaussian peaks. For the temperature driven first order transition in the thermodynamic limit, the locus and the angular density of zeros are given by and respectively in the complex -plane where is the reduced latent heat, is the discontinuity in the reduced specific heat and .
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Taxonomy
TopicsMaterial Dynamics and Properties · Phase Equilibria and Thermodynamics · Theoretical and Computational Physics
