Buckling Instabilities of a Confined Colloid Crystal Layer

TL;DR

This paper models the buckling transitions of confined colloidal crystal layers, predicting phase behaviors and symmetries that can be experimentally observed, with implications for understanding phase transitions in confined colloids.

Contribution

It introduces a thermodynamic model for buckling instabilities in confined colloidal layers, linking structural transitions to well-known statistical models.

Findings

Identification of three distinct buckling-induced structures.

Prediction of second order phase transitions with specific symmetries.

Connection of phase behavior to Potts, XY, and Heisenberg models.

Abstract

A model predicting the structure of repulsive, spherically symmetric, monodisperse particles confined between two walls is presented. We study the buckling transition of a single flat layer as the double layer state develops. Experimental realizations of this model are suspensions of stabilized colloidal particles squeezed between glass plates. By expanding the thermodynamic potential about a flat state of \( N \) confined colloidal particles, we derive a free energy as a functional of in-plane and out-of-plane displacements. The wavevectors of these first buckling instabilities correspond to three different ordered structures. Landau theory predicts that the symmetry of these phases allows for second order phase transitions. This possibility exists even in the presence of gravity or plate asymmetry. These transitions lead to critical behavior and phases with the symmetry of the three-state and four-state Potts models, the X-Y model with 6-fold anisotropy, and the Heisenberg model with cubic interactions. Experimental detection of these structures is discussed.