Surface Effects on Bulk Plasmons
Olle Heinonen, Walter Kohn

TL;DR
This paper investigates how surfaces influence bulk plasma oscillations in metallic films, deriving corrections to plasma frequencies and dispersion relations, and analyzing resonant excitation effects.
Contribution
It provides a new explicit expression for the surface characteristic length $d_b$ and explores surface-induced corrections to bulk plasmon properties.
Findings
Surface corrections to plasma frequencies are proportional to $L^{-1}$.
Derived a dispersion relation incorporating surface effects.
Calculated resonant excitation of bulk plasmons by external fields.
Abstract
We discuss the effects of surfaces on bulk plasma oscillations in a metallic film of thickness . The leading corrections to the plasma frequencies due to the surfaces are proportional to . dispersion relation of bulk modes, , where the allowed -values are , , and is a complex length characteristic of the surface (reminiscent of but different from Feibelman's ). An explicit expression for is derived. Resonant excitation by an external field, , is calculated.
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