Stability of Jahn Teller distortion in LaMnO3 under pressure: An x-ray absorption study

TL;DR

This study investigates how Jahn-Teller distortions in LaMnO3's MnO6 octahedra respond to high pressure using x-ray absorption spectroscopy, revealing persistent distortions up to 15.3 GPa and potential metallization at higher pressures.

Contribution

It provides the first detailed analysis of Jahn-Teller distortion stability in LaMnO3 under pressure using x-ray absorption spectroscopy.

Findings

Distortion persists up to 15.3 GPa

Reduction in Mn-O distance begins above 8 GPa

Hysteresis indicates coexistence of distorted and undistorted units

Abstract

The local environment of manganese atoms in LaMnO3 under pressure up to 15.3 GPa has been studied by x-ray absorption spectroscopy. For pressures below 8 GPa, no change is detected within the MnO6 octahedra. Above this pressure a continuous reduction of the long Mn-O distance takes place, however the octahedral distortion persists over the whole pressure range. At 15.3 GPa the average Jahn-Teller splitting of the distances is reduced by about one third, indicating that a total removal of the local Jahn-Teller distortion would occur only for pressures around 30 GPa, where metallization is reported to take place. A hysteresis in the long distance reduction is observed down to ambient pressure, suggesting the coexistence of MnO6 distorted and undistorted units.