Electronic Structure of Spin-Chain Compounds: Common Features

TL;DR

This study uses density functional theory to analyze the electronic structure of incommensurate spin-chain compounds, revealing that chains and ladders can be treated independently and identifying key electronic features at the Fermi level.

Contribution

The paper demonstrates that chains and ladders in M14Cu24O41 compounds can be modeled separately, simplifying the understanding of their electronic structures.

Findings

Chains and ladders can be treated independently.

Two characteristic bands at the Fermi energy in CuO2 chains.

Nearest and next-nearest neighbor interactions are comparable.

Abstract

The incommensurate composite systems M14Cu24O41 (M=Ca,Sr,La) are based on two fundamental structural units: CuO2 chains and Cu2O3 ladders. We present electronic structure calculations within density functional theory in order to address the interrelations between chains and ladders. The calculations account for the details of the crystal structure by means of a unit cell comprising 10 chain and 7 ladder units. It turns out that chains and ladders can be treated independently, which allows us to introduce a model system based on a reduced unit cell. For the CuO2 chains, we find two characteristic bands at the Fermi energy. Tight binding fits yield nearest and next-nearest neighbour interactions of the same order of magnitude.