High critical current density and improved flux pinning in bulk MgB2 synthesized by Ag addition

TL;DR

This study demonstrates that adding silver to MgB2 enhances its critical current density and flux pinning by forming MgAg nanoparticles, improving superconducting performance at various magnetic fields.

Contribution

It introduces a systematic investigation of Ag addition in MgB2, revealing optimal doping levels and microstructural features that improve superconducting properties.

Findings

Maximum intragrain Jc of 9.23x10^7 A/cm^2 at 5K for 10% Ag doping

MgAg nanoparticles (~5-20 nm) enhance flux pinning

Ag admixing significantly improves Jc compared to pure MgB2

Abstract

In the present investigation, we report a systematic study of Ag admixing in MgB2 prepared by solid-state reaction at ambient pressure. All the samples in the present investigation have been subjected to structural/ microstructural characterization employing x-rays diffraction (XRD) and transmission electron microscopic (TEM) techniques. The magnetization measurements were performed by physical property measurement system (PPMS). The TEM investigations reveal the formation of MgAg nanoparticles in Ag admixed samples. These nanoparticles may enhance critical current density due to their size (~5-20 nm) compatible with coherence length of MgB2 (~5-6 nm). In order to study the flux pinning effect of Ag admixing in MgB2, the evaluation of intragrain critical current density (Jc) has been carried out through magnetic measurements on the fine powdered version of the as synthesized samples. The optimum result on intragrain Jc is obtained for 10 at.% Ag admixed sample at 5K. This corresponds to 9.23x10^7 A/cm^2 in self-field,5.82x10^7 A/cm^2 at 1T,4.24 x10^6 A/cm^2 at 3.6T and 1.52x10^5 A/cm^2 at 5T. However, intragrain Jc values for MgB2 sample without Ag admixing are 2.59x10^6 A/cm^2,1.09x10^6A/cm^2,4.53x10^4 A/cm^2 and 2.91x10^3A/cm^2 at 5 K in self field, 1T, 3.6T and 5T respectively.. The high value of intragrain Jc for Ag admixed MgB2 superconductor has been attributed to the inclusion of MgAg nanoparticles into the crystal matrix of MgB2, which are capable of providing effective flux pinning centres. A feasible correlation between microstructural features and superconducting properties has been put forward.