Universality in one dimensional orbital wave ordering in spinel and related compounds: an experimental perspective

TL;DR

This paper proposes a unifying one-dimensional orbital wave ordering scheme for spinel compounds, explaining diverse local bonding units through orbital phase and amplitude, supported by crystallographic data.

Contribution

It introduces a general orbital wave ordering framework applicable to various spinel compounds with local triangular transition metal coordination.

Findings

Orbital phase and amplitude are crucial for local bonding unit formation.

The scheme explains dimer, octomer, and heptamer formations in different spinels.

The model extends to related compounds with similar structural features.

Abstract

Recent state-of-the-art crystallographic investigations of transition metal spinel compounds have revealed that the d- orbital charge carriers undergo ordering transitions with the formation of local "molecular bonding" units such as dimers in MgTi2O4, octomers in CuIr2S4, and heptamers in AlV2O4. Herein, we provide a unifying scheme involving one- dimensional orbital wave ordering applicable to all of these spinels. The relative phase of the orbitals in the chains is shown to be crucial to the formation of different local units, and thus both the amplitude and phase of the orbital wave play important roles. Examination of Horibe et al.'s [1] structure for AlV2O4 serves as the vehicle for developing the general behavior for such orbital wave ordering. Ordered AlV2O4 will be seen to organize into three equivalent chains in 2D Kagome planes coupled so as to form units of three dimer bonds. Three additional equivalent chains manifest a more complex tetramerization with three different charge states and two different bonding schemes. The orbital wave ordering scheme developed is extended to other spinel and related compounds with local triangular transition metal coordination and partial filling of the t2g-d orbitals.