Critical cooling rate for the glass formation of ferromagnetic Fe40Ni40P14B6 alloy

TL;DR

This study estimates the critical cooling rate for forming bulk amorphous Fe40Ni40P14B6 alloy using rapid solidification, finding it around 492.4 K/s, consistent with CCT curve estimates, indicating impurity elimination.

Contribution

The paper provides an experimental estimate of the critical cooling rate for Fe40Ni40P14B6 alloy using finite-difference calculations and CCT curve analysis.

Findings

Critical cooling rate estimated at ~492.4 K/s.

Largest amorphous specimen diameter was ~2.5 mm.

Impurities were effectively eliminated in the process.

Abstract

Bulk ferromagnetic amorphous Fe-Ni-P-B alloys in rod shape were formed by a rapid solidification technique. The largest amorphous specimen prepared had a diameter of ~2.5 mm and the corresponding cooling rate for the glass formation of this alloy system in our experiment can be estimate to be around 492.4 K/s by the method of finite-difference numerical calculation. This value is on the same order of magnitude as the critical cooling rate Rc of Fe40Ni40P14B6 alloy estimated by the method of constructing the continuous-cooling-transformation (CCT) curve. It is indicated that the heterophase impurities have been eliminated well in our experiment.