Force balance of particles trapped at fluid interfaces

TL;DR

This paper investigates the forces between particles at fluid interfaces under pressure, comparing the force approach to the energy approach, and explores how interface deformations affect particle interactions and positions.

Contribution

It introduces a stress-tensor formulation of forces at fluid interfaces, compares force and energy methods, and analyzes particle-induced deformations on curved interfaces.

Findings

Force approach relies on mechanical equilibrium, less restrictive than energy approach.

Derived an electrostatics analogy for small interface deformations.

Found capillary forces unlikely to explain some experimental results.

Abstract

We study the effective forces acting between colloidal particles trapped at a fluid interface which itself is exposed to a pressure field. To this end we apply what we call the ``force approach'', which relies solely on the condition of mechanical equilibrium and turns to be in a certain sense less restrictive than the more frequently used ``energy approach'', which is based on the minimization of a free energy functional. The main goal is to elucidate the advantages and disadvantages of the force approach as compared to the energy approach. First, we derive a general stress-tensor formulation of the forces at the interface and work out a useful analogy with 2D electrostatics in the particular case of small deformations of the interface relative to its flat configuration. We apply this analogy to compute the asymptotic decay of the effective force between particles trapped at a fluid interface, extending the validity of previous results. Second, we address the case of deformations of a non-flat interface. We compute the deformation of a spherical droplet due to the electric field of a charged particle trapped at its surface and conclude that the interparticle capillary force is unlikely to explain certain recent experimental observations. Finally we discuss the application to a generally curved interface and show as an illustrative example that a nonspherical particle deposited on an interface forming a minimal surface is pulled to regions of larger curvature.