Intermediate phase in the oxidative hydrothermal synthesis of potassium jarosite, a model kagome antiferromagnet

TL;DR

This paper introduces a new oxidative hydrothermal synthesis method for potassium jarosite, revealing a metastable intermediate that enables high iron coverage and potentially allows synthesis of hydronium jarosite, a spin glass with exotic magnetic states.

Contribution

The study uncovers a novel synthesis mechanism involving a metastable intermediate, improving iron coverage in jarosite minerals and enabling new magnetic material synthesis.

Findings

Identification of a metastable intermediate via powder X-ray diffraction

High Fe coverage achieved in potassium, sodium, rubidium, and ammonium jarosites

Potential to synthesize hydronium jarosite with unique magnetic properties

Abstract

The jarosite family of minerals contain antiferromagnetically coupled Fe3+ ions that make up the kagome network. This geometric arrangement of the Fe3+ ions causes magnetic frustration that results in exotic electronic ground states, e.g. spin glasses and spin liquids. Synthesic research into jarosites has focused on producing near perfect stoichiometry to eliminate possible magnetic disorder. An new oxidative synthesis method has been devel-oped for the potassium, sodium, rubidium and ammonium jarosites that leads to high Fe coverage. We show through the identification of a meta-stable intermediate, using powder X-ray diffraction, how near perfect Fe coverage arises using this method. Understanding this new mechanism for jarosite formation suggests that is it possible to synthesis hydronium jarosite, an unconventional spin glass, with a very high Fe coverage.