Magnetic phases in the Kagome staircase compound Co3V2O8

TL;DR

This study investigates the magnetic phases of Co3V2O8 using neutron diffraction, revealing field-induced moment enhancement and phase transitions from incommensurate antiferromagnetic to ferromagnetic order.

Contribution

It provides detailed insights into the magnetic structure and field response of Co3V2O8, including a simple spin rotation model and temperature-dependent phase behavior.

Findings

Zero-field ferromagnetic ground state below 6 K

Magnetic field enhances cross-tie site moments

Transition from incommensurate antiferromagnetic to ferromagnetic order at higher temperatures

Abstract

The low temperature properties of the Kagome-type system Co3V2O8 have been studied by powder neutron diffraction both in zero field and in applied magnetic field of up to 8 T. Below 6 K, the zero-field ground state is ferromagnetic with the magnetic moments aligned along the a-axis. The size of the moment on one of the two Co sites, the so called cross-tie site, is considerably reduced compared to the fully polarized state. The application of a magnetic field in this phase is found to rapidly enhance the cross-tie site magnetic moment, which reaches the expected value of ~3muB by the maximum applied field of 8 T. Different reorientation behaviors are found for the Co cross-tie and spine sites, suggesting a more pronounced easy-axis anisotropy for moments on the spine sites. Rietveld refinements reveal that a simple model, where the spins on both cross-tie and spine sites rotate in the ac-plane in a magnetic field, reproduces the experimental diffraction patterns well. In addition, it is found that at higher temperatures and moderate magnetic fields, the incommensurate antiferromagnetic order, corresponding to a transverse sinusoidal modulation above 8 K, is suppressed to be replaced by ferromagnetic order.