Relative entropy, Haar measures and relativistic canonical velocity distributions
J\"orn Dunkel, Peter Talkner, Peter H\"anggi

TL;DR
This paper reexamines the maximum entropy principle using group and measure theory, linking relativistic velocity distributions to invariance properties of reference measures, and introduces a modified Jüttner distribution based on Lorentz invariance.
Contribution
It demonstrates how the maximum entropy principle can be understood through relative entropy and invariance, leading to a new relativistic velocity distribution consistent with Lorentz symmetry.
Findings
Standard Jüttner distribution relates to translation invariance in momentum space.
Imposing Lorentz invariance yields a modified distribution with a different prefactor.
The approach unifies thermodynamic principles with symmetry considerations in relativistic systems.
Abstract
The thermodynamic maximum principle for the Boltzmann-Gibbs-Shannon (BGS) entropy is reconsidered by combining elements from group and measure theory. Our analysis starts by noting that the BGS entropy is a special case of relative entropy. The latter characterizes probability distributions with respect to a pre-specified reference measure. To identify the canonical BGS entropy with a relative entropy is appealing for two reasons: (i) the maximum entropy principle assumes a coordinate invariant form; (ii) thermodynamic equilibrium distributions, which are obtained as solutions of the maximum entropy problem, may be characterized in terms of the transformation properties of the underlying reference measure (e.g., invariance under group transformations). As examples, we analyze two frequently considered candidates for the one-particle equilibrium velocity distribution of an ideal gas of…
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