Spin-flop transition in uniaxial antiferromagnets: magnetic phases, reorientation effects, multidomain states

TL;DR

This paper develops a comprehensive phenomenological theory for the spin-flop transition in uniaxial antiferromagnets, highlighting the complex phase structure, multidomain states, and measurable susceptibility anomalies near the transition.

Contribution

It introduces a detailed effective model accounting for higher-order anisotropy and dipolar fields, and applies it to experimental data on layered antiferromagnets.

Findings

Multidomain states exist in the spin-flop region due to phase coexistence.

Susceptibility tensor components show anomalies near the spin-flop.

The theory accurately describes experimental magnetic properties in antiferromagnets.

Abstract

The classical spin-flop is the field-driven first-order reorientation transition in easy-axis antiferromagnets. A comprehensive phenomenological theory of easy-axis antiferromagnets displaying spin-flops is developed. It is shown how the hierarchy of magnetic coupling strengths in these antiferromagnets causes a strongly pronounced two-scale character in their magnetic phase structure. In contrast to the major part of the magnetic phase diagram, these antiferromagnets near the spin-flop region are described by an effective model akin to uniaxial ferromagnets. For a consistent theoretical description both higher-order anisotropy contributions and dipolar stray-fields have to be taken into account near the spin-flop. In particular, thermodynamically stable multidomain states exist in the spin-flop region, owing to the phase coexistence at this first-order transition. For this region, equilibrium spin-configurations and parameters of the multidomain states are derived as functions of the external magnetic field. The components of the magnetic susceptibility tensor are calculated for homogeneous and multidomain states in the vicinity of the spin-flop. The remarkable anomalies in these measurable quantities provide an efficient method to investigate magnetic states and to determine materials parameters in bulk and confined antiferromagnets, as well as in nanoscale synthetic antiferromagnets. The method is demonstrated for experimental data on the magnetic properties near the spin-flop region in the orthorhombic layered antiferromagnet (C_2H_5NH_3)_2CuCl_4.