Magnetic and magnetoresistance behavior of Tb7Rh3, an intermetallic compound with a negative temperature coefficient of electrical resistivity in the paramagnetic state, and Paramagnetic Giant Magnetoresistance Phenomenon

TL;DR

This study investigates Tb7Rh3, revealing its complex magnetic transitions, negative resistivity temperature coefficient in the paramagnetic state, and large magnetoresistance effects, including paramagnetic giant magnetoresistance, across a wide temperature range.

Contribution

It reports the first detailed measurements of magnetic, electrical, and heat capacity properties of Tb7Rh3, highlighting its unique magnetoresistance behavior and the ability to tune resistivity sign with magnetic field.

Findings

Negative dR/dT in paramagnetic state over wide temperature range

Large magnetoresistance near room temperature

Magnetic field can change the sign of dR/dT

Abstract

The results of dc magnetization, electrical and magnetoresistance and heat capacity measurements (2-300 K) on Tb7Rh3, crystallizing in Th7Fe3-type hexagonal structure, are reported. In this compound, magnetic ordering sets in around 90 K with additional transitions at low temperatures and the temperature coefficient of resistivity (R), dR/dT, is negative over a wide temperature range in the paramagnetic state. The present magnetization results reveal that this compound is apparently characterized by rich features in the magnetic-field-temperature phase diagram. A point of major emphasis is that the sign of dR/dT in the paramagnetic state can be gradually changed by the application of magnetic field. As a result, the magnitude of the magnetoresistance (MR) is rather large even in the vicinity of room temperature (far above magnetic ordering temperature), in addition to giant MR behavior in the magnetically ordered state. Viewed together With similar behavior for other heavy rare-earth members of this series, this class of compounds can be classified as Paramagnetic Giant Magnetoresistance Systems. A new theoretical approach is warranted to understand this phenomenon.