Electrical conductivity of cellular Si/SiC ceramic composites prepared from plant precursors

TL;DR

This study investigates the electrical conductivity and thermoelectric properties of bio-template derived Si/SiC ceramic composites, revealing their anisotropic conduction behavior and VRH mechanism, with potential for electrical applications.

Contribution

It introduces a biomimetic route to produce Si/SiC composites with enhanced electrical properties and anisotropic conductivity, comparable or superior to conventional methods.

Findings

Electrical conductivity is nearly temperature-independent.

Conductivity anisotropy ratio is approximately 2.

Charge conduction follows variable range hopping (VRH) mechanism.

Abstract

Electrical conductivity (sigma_dc) of the cellular Si/SiC ceramic composites has been measured over a temperature range 25-1073 K while the thermoelectric power (S) has been measured over 25-300 K. Remarkably, these cellular compounds developed through biomimetic route - where the ceramic system grows within a plant bio-template retaining the structural intricacies of the native templates - are found to exhibit excellent mechanical, thermal, and electrical properties quite comparable to or even better than those of the systems prepared through conventional ceramic route. The electrical conductivity measured parallel (sigma||) and perpendicular (sigma+) to the growth axes of the native plants, depicts nearly temperature-independent anisotropy (sigma+/sigma||) of the order \~2 while the thermoelectric power is nearly isotropic. The charge conduction across the entire temperature range is found to follow closely the variable range hopping (VRH) mechanism. The conductivity anisotropy appears to be driven primarily by the unique microcellular morphology of the bio-templates which can be exploited in many electrical applications.