Inelastic Light Scattering From Correlated Electrons

TL;DR

This review discusses how inelastic light scattering, especially Raman spectroscopy, provides unique insights into the anisotropic and complex many-body behavior of correlated electrons in various materials, complementing other experimental methods.

Contribution

It offers a comprehensive overview of recent theoretical and experimental advances in electronic Raman scattering in correlated systems, highlighting its role in understanding electron dynamics.

Findings

Raman scattering reveals anisotropic electron behavior in correlated materials.

Recent theories connect Raman response to electron correlations and competing orders.

Experimental results in superconductors and insulators demonstrate the method's effectiveness.

Abstract

Inelastic light scattering is an intensively used tool in the study of electronic properties of solids. Triggered by the discovery of high temperature superconductivity in the cuprates and by new developments in instrumentation, light scattering both in the visible (Raman effect) and the X-ray part of the electromagnetic spectrum has become a method complementary to optical (infrared) spectroscopy while providing additional and relevant information. The main purpose of the review is to position Raman scattering with regard to single-particle methods like angle-resolved photoemission spectroscopy (ARPES), and other transport and thermodynamic measurements in correlated materials. Particular focus will be placed on photon polarizations and the role of symmetry to elucidate the dynamics of electrons in different regions of the Brillouin zone. This advantage over conventional transport (usually measuring averaged properties) indeed provides new insights into anisotropic and complex many-body behavior of electrons in various systems. We review recent developments in the theory of electronic Raman scattering in correlated systems and experimental results in paradigmatic materials such as the A15 superconductors, magnetic and paramagnetic insulators, compounds with competing orders, as well as the cuprates with high superconducting transition temperatures. We present an overview of the manifestations of complexity in the Raman response due to the impact of correlations and developing competing orders. In a variety of materials we discuss which observations may be understood and summarize important open questions that pave the way to a detailed understanding of correlated electron systems.