Tube-Tube and Tube-Surface Interactions in Straight Suspended Carbon Nanotube Structures

TL;DR

This study investigates how interactions between carbon nanotubes and with their growth surface influence their tautness, revealing a zipper effect that affects nanotube alignment and buckling, with implications for controlled CNT network fabrication.

Contribution

It uncovers the primary role of tube-tube and tube-surface interactions in CNT tautness, providing insights for tuning nanotube alignment during CVD growth.

Findings

Tube-tube and tube-surface interactions cause tautness.

Interactions induce a zipper effect that straightens nanotubes.

Strong interactions can cause wide tubes to buckle.

Abstract

An investigation concerning the tautness of suspended carbon nanotubes (CNTs), grown using the chemical vapor deposition (CVD) method is presented. The suspended nanotubes were analyzed with both a transmission electron microscope (TEM), and a high resolution scanning electron microscope (HR-SEM). The HR-SEM and TEM investigations revealed that the interactions between CNTs among themselves, and with the surface on which they are grown, is a primary cause for the tautness of suspended tubes. Specifically, the tube-tube and tube-surface dynamics cause adjoining tubes to create a zipper effect, thereby straightening and tightening them. Suspended CNTs cling to each other, and to as much of the surface as possible, in order to minimize their total energy, creating taut, suspended structures. This effect can be so strong so as to force wide tubes to buckle, with no other external force involved. The implications of this study include all forms of alignment processes of nanotubes using the CVD method. The results presented here provide the groundwork for the capability of fine-tuning the control of CNT network formation using substrate mechanical features.