Dissipative Van der Waals interaction between a small particle and a metal surface

TL;DR

This paper develops a comprehensive theory to calculate electromagnetic friction forces on small particles near metal surfaces, considering various physical effects, and highlights its significance in energy relaxation and surface heating.

Contribution

It introduces a general framework for calculating electromagnetic friction on particles near metals, accounting for temperature, separation, and material properties, including screening and retardation effects.

Findings

Dissipative van der Waals interaction can significantly relax vibrational energy of molecules.

Electromagnetic friction influences microscopic solid interactions and energy dissipation.

Surface local heating by STM tips can be affected by electromagnetic dissipative shear stress.

Abstract

We use a general theory of the fluctuating electromagnetic field to calculate the friction force acting on a small neutral particle, e.g., a physisorbed molecule, or a nanoscale object with arbitrary dispersive and absorptive dielectric properties, moving near a metal surface. We consider the dependence of the electromagnetic friction on the temperature $T$, the separation $d$, and discuss the role of screening, non-local and retardation effects. We find that for high resistivity materials, the dissipative van der Waals interaction can be an important mechanism of vibrational energy relaxation of physisorbed molecules, and friction for microscopic solids. Several controversial topics related to electromagnetic dissipative shear stress is considered. The problem of local heating of the surface by an STM tip is also briefly commented on.