Thermopower of CexR1-xB6 (R=La, Pr and Nd)

TL;DR

This study investigates the thermopower of CexR1-xB6 (R=La, Pr, Nd), revealing how the Kondo effect and chemical pressure influence thermoelectric properties across different compositions and phases.

Contribution

It provides a comparative analysis of thermopower behavior in CexR1-xB6 systems, highlighting differences due to R substitution and phase transitions, which was not previously detailed.

Findings

High-temperature S roughly linearly depends on Ce concentration

T_max decreases with decreasing x in CexLa1-xB6

S_max decreases linearly with x in CexR1-xB6 (R=Pr, Nd)

Abstract

The thermopower, S, of CexR1-xB6 (R=La, Pr, Nd) was investigated. S with a positive sign shows a typical behavior observed in the Ce Kondo system, an increase with decreasing temperature at high temperatures and a maximum at low temperatures. The S values of all the systems at high temperatures are roughly linearly dependent on the Ce concentration, indicating the conservation of the single-impurity character of the Kondo effect in a wide x range. However, the maximum value of S, S_max, and the temperature, T_max, at which S_max is observed exhibit different x dependences between CexLa1-xB6 and CexR1-xB6 (R=Pr, Nd). In CexLa1-xB6, T_max, which is ~8 K in CeB6, decreases with decreasing x and converges to ~1 K in a very dilute alloy and S_max shows an increase below x ~ 0.1 after decreasing with decreasing x. In CexR1-xB6 (R=Pr, Nd), T_max shows a weak x dependence but S_max shows a roughly linear decrease in x. These results are discussed from the standpoint of the chemical pressure effect and the Ce-Ce interaction. S in the long-range ordered phase shows very different behavior between CexPr1-xB6 and CexNd1-xB6.