Role of magnetic and orbital ordering at the metal-insulator transition in NdNiO3

TL;DR

This study uses soft x-ray resonant scattering to investigate magnetic and orbital ordering in NdNiO3, revealing a non-collinear magnetic structure and absence of orbital order at the metal-insulator transition.

Contribution

It provides new insights into the magnetic structure and confirms the lack of orbital ordering in NdNiO3 during the transition.

Findings

Non-collinear magnetic structure identified

Absence of orbital order at transition

Resonant scattering reveals magnetic details

Abstract

Soft x-ray resonant scattering at the Ni L2,3 edges is used to test models of magnetic and orbital-ordering below the metal-insulator transition in NdNiO3. The large branching ratio of the L3 to L2 intensities of the (1/2,0,1/2) reflection and the observed azimuthal angle and polarization dependence originates from a non collinear magnetic structure. The absence of an orbital signal and the non collinear magnetic structure show that the nickelates are materials for which orbital ordering is absent at the metal-insulator transition.