The Parent of Misfit-Layered Cobalt Oxides: [Sr2O2]qCoO2

TL;DR

This paper reports the discovery of a new, simple misfit-layered cobalt oxide phase, [Sr2O2]qCoO2, which exhibits promising thermoelectric properties similar to more complex derivatives, expanding understanding of ML cobalt oxides.

Contribution

The study introduces the simplest misfit-layered cobalt oxide phase in the Sr-Co-O system, providing structural and transport property insights that broaden the scope of thermoelectric materials.

Findings

New phase Sr2O2CoO2 confirmed by TEM and electron diffraction.

The phase has a commensurate misfit parameter q of 0.5.

Transport properties are comparable to complex derivatives.

Abstract

Misfit-layered (ML) cobalt oxides of the general formula of [MmA2Om+2]qCoO2 have been proven to be efficient thermoelectric materials as the structure is capable in accommodating the two seemingly contradictory characteristics of high electrical conductivity and large thermo-electric power. They are also potential hosts for other oxymoron-like functions. The known phases all contain one or two square-planar MO (M = Co, Bi, Pb, Tl, etc.) layers sandwiched together with AO (A = Ca, Sr, Ba, etc.) planes of square symmetry and CoO2 layers of hexagonal symmetry. Here we report realization of the simplest (m = 0) ML phase forming in the Sr-Co-O system with the cation ratio, Sr/Co = 1. Atomic-resolution TEM imaging confirms for the new phase the parent three-layer crystal structure, SrO-SrO-CoO2, which is compatible with the formula of [Sr2O2]qCoO2. Electron diffraction reveals that the phase is rather commensurate, i.e. the "misfit parameter" q is 0.5. Nevertheless, in terms of the transport-property characteristics the new ML parent is comparable to its earlier-established and more complex derivatives.