Temperature Dependence of the Chemical Potential in NaxCoO2: Implications for the Large Thermoelectric Power

TL;DR

This study investigates how the chemical potential in NaxCoO2 changes with temperature, revealing a crossover from degenerate fermion behavior to correlated hopping, which impacts thermoelectric power understanding.

Contribution

It provides the first temperature-dependent photoemission analysis of NaxCoO2 epitaxial thin films, linking chemical potential shifts to thermoelectric properties.

Findings

Chemical potential shifts with temperature were measured.

A crossover from degenerate to correlated hopping states was observed.

Implications for thermoelectric power at high temperatures were discussed.

Abstract

We have performed a temperature-dependent photoemission study of a NaxCoO2 (x~0.8) epitaxial thin film prepared by the reactive solid-phase epitaxy method. The chemical potential shift as a function of temperature was derived from the Co 3d peak shift, and revealed a crossover from the degenerate Fermion state at low temperatures to the correlated hopping state of Co3+/Co4+ mixed-valence at high temperatures. This suggests that the large thermoelectric power at high temperatures should be considered in the correlated hopping picture.