Monolayer charged quantum films: A quantum simulation study

TL;DR

This study uses quantum Monte Carlo simulations to explore how long-range Coulomb repulsion influences phase behavior in monolayer quantum films, revealing complex phases like Wigner crystals and stripe order.

Contribution

It introduces a detailed simulation of competing Van der Waals and Coulomb interactions in monolayer quantum films, highlighting new phase transitions and quantum fluctuation effects.

Findings

Formation of Wigner-like crystal of clusters

Emergence of charge stripe-ordered phase

Presence of a fluid phase under certain conditions

Abstract

We use path-integral Monte Carlo (PIMC) to study the effects of adding a long-range repulsive Coulomb interaction to the usual Van der Waals interaction between two atoms of a submonolayer quantum film such as helium on graphite or a pure two-dimensional superfluid. Such interactions frustrate or compete with the natural tendency of the system for phase separation namely to form a macroscopic liquid or solid phase. We find that as a function of the relative strength of the long-range repulsion, surface coverage and temperature, the system undergoes a series of transformations, including a triangular Wigner-like crystal of clusters, a charge stripe-ordered phase and a fluid phase. The goal of these studies is to understand the role of quantum fluctuations when such competing interactions appear together with formation of preexisting electron pairs as might be the case in cuprate superconductors.