A Nonequilibrium Thermodynamic Approach to Generalized Statistics for Brownian Motion

TL;DR

This paper develops a nonequilibrium thermodynamic framework to describe large temperature fluctuations in a Brownian gas, leading to a nonextensive hydrodynamic model with fluctuating transport coefficients.

Contribution

It introduces a novel nonequilibrium thermodynamics approach with local equilibrium formulation to derive an effective Maxwell-Boltzmann factor and a nonextensive hydrodynamic description for Brownian motion.

Findings

Derived an effective Maxwell-Boltzmann factor (EMBF) for Brownian gas.

Established a nonextensive hydrodynamic model with fluctuating transport coefficients.

Showed coarse-graining causes nonextensivity in the system.

Abstract

We analyze the dynamics of a Brownian gas in contact with a heat bath in which large temperature fluctuations occur. There are two distinct time scales present, one describes the decay of the fluctuations in the temperature and the other one is associated with the establishment of local equilibrium. Although the gas has reached local equilibrium, there exist large fluctuations in an intensive parameter (temperature) which break the thermodynamic equilibrium with the heat bath. Thus the decay of the fluctuations in the intensive parameter is larger than the characteristic time for the establishment of local equilibrium. We show that the dynamics of such large and intensive fluctuations may be described by adopting a nonequilibrium thermodynamics approach with an adequate formulation of local equilibrium. A coarsening procedure is then used to contract the space of mesoscopic variables needed to describe the dynamics of the gas and the extensive character of the description is lost. This procedure allows us to derive an effective Maxwell-Boltzmann factor (EMBF) for the Brownian gas, as has been recently proposed in the literature. Furthermore, we use this local equilibrium distribution and an entropy functional to derive a nonequilibrium probability distribution and a hydrodynamic description for the Brownian gas which contains fluctuating transport coefficients. The ensuing description is nonextensive and our analysis shows that the coarse-graining procedure is responsible for the nonextensivity property.