Magnetic Phase Transition at 88 K in Na0.5CoO2 revealed by 23Na-NMR investigations

TL;DR

This study reveals a magnetic phase transition at 88 K in Na0.5CoO2 through 23Na-NMR, showing magnetic ordering precedes charge ordering and the metal-insulator transition.

Contribution

It provides detailed NMR evidence of a magnetic transition at 88 K and clarifies its relation to charge ordering in Na0.5CoO2.

Findings

Magnetic ordering occurs below 88 K without charge rearrangement.

The transition at 88 K is reflected in NMR spectra and relaxation rates.

Magnetic order precedes the metal-insulator transition.

Abstract

Na0.5CoO2 exhibits a metal-insulator transition at 53 K upon cooling. The nature of another transition at 88 K has not been fully clarified yet. We report the results of measurements of the electrical conductivity, the magnetic susceptibility and 23Na NMR on a powder sample of Na0.5CoO2, including the mapping of NMR spectra, as well as probing the spin-lattice relaxation rate and the spin-spin relaxation rate, in the temperature range between 30 K and 305 K. The NMR data reflect the transition at T_X very well but provide less evidence for the metal-insulator transition at T_MI. The temperature evolution of the shape of the spectra implies the formation of a staggered internal field below T_X, not accompained by a rearrangement of the electric charge distribution. Our results thus indicate that in Na0.5CoO2, an unusual type of magnetic ordering in the metallic phase precedes the onset of charge ordering, which finally induces an insulating ground state.