CaCu_3Ti_4O_12/CaTiO_3 Composite Dielectrics: A Ba/Pb-free Ceramics with High Dielectric Constants

TL;DR

This study reports a Ba/Pb-free composite ceramic with high dielectric constant and low dissipation, suitable for environmentally friendly electronic applications.

Contribution

It introduces a new CaCu3Ti4O12/CaTiO3 composite dielectric with superior properties compared to traditional Pb/Ba-based ceramics.

Findings

Dielectric constant of 1800 below 100 kHz

Low dissipation factor of 0.02

Comparable or better than Pb/Ba-based ceramics

Abstract

We have measured dielectric properties of Ca$_{1+x}$Cu$_{3-x}$Ti$_4$O$_{12}$ ($x$ = 0, 0.1, 0.5, 1, 1.5, 2, 2.9 and 3), and have found that Ca$_2$Cu$_2$Ti$_4$O$_{12}$ (a composite of CaCu$_3$Ti$_4$O$_{12}$ and CaTiO$_3$) exhibits a high dielectric constant of 1800 with a low dissipation factor of 0.02 below 100 kHz from 220 to 300 K. These are comparable to (or even better than) those of the Pb/Ba-based ceramics, which could be attributed to a barrier layer of CaTiO$_3$ on the surface of the CaCu$_3$Ti$_4$O$_{12}$ grains. The composite dielectric ceramics reported here are environmentally benign as they do not contain Ba/Pb.