An organometallic chimie douce approach to new Re(x)W(1-x)O3 phases
Christian Helbig, Rudolf Herrmann, Franz Mayr, Ernst-Wilhelm Scheidt,, Klaus Troester, Jan Hanss, Hans-Albrecht Krug von Nidda, Wolfgang Scherer
TL;DR
This paper introduces a novel organometallic chimie douce method to synthesize new Re(x)W(1-x)O3 phases using methyltrioxorhenium as a precursor, expanding the materials' synthesis techniques.
Contribution
It presents a new synthesis approach for Re(x)W(1-x)O3 phases based on organometallic chimie douce, which was not previously reported.
Findings
Successful synthesis of Re(x)W(1-x)O3.H2O and Re(x)W(1-x)O3 phases
Use of methyltrioxorhenium as a precursor in a new method
Potential for new material properties and applications
Abstract
Re(x)W(1-x)O3.H2O and Re(x)W(1-x)O3 phases are prepared by a new organometallic chimie douce concept employing the organometallic precursor methyltrioxorhenium.
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Taxonomy
TopicsPolyoxometalates: Synthesis and Applications · Catalysis and Oxidation Reactions · Catalytic Processes in Materials Science