Magnetic and superconducting properties of RuSr2 Gd1.5Ce0.5Cu2O10-x samples: dependence on the oxygen content and ageing effects

TL;DR

This study investigates how oxygen content and aging influence the magnetic and superconducting properties of RuSr2Gd1.5Ce0.5Cu2O10-x, revealing that oxygen depletion suppresses superconductivity and enhances spin glass behavior, with properties also evolving over time.

Contribution

It provides new insights into the effects of oxygen doping and aging on the magnetic and superconducting phases of Ru-based cuprates.

Findings

Superconducting temperature decreases with oxygen reduction.

Spin glass transition shifts to higher temperatures with less oxygen.

Properties change significantly over time, indicating aging effects.

Abstract

The magnetic and superconducting properties of RuSr2Gd1.5Ce0.5Cu2O10-x polycrystalline samples with different oxygen doping level are presented. A strong suppression of the superconducting temperature (Tc), as well as a reduction in the superconducting fraction, occurs as the oxygen content is reduced by annealing the samples in oxygen deprived atmospheres. Drastic changes in the electrical resistivity are observed above Tc, possibly associated with oxygen removal mainly from grain boundaries. However, the magnetic ordering is relatively less affected by the changes in oxygen content of the samples. The spin glass transition is enhanced and shifted to higher temperatures with the reduction in oxygen content. This could be correlated with an increase in the spins disorder and frustration for the oxygen depleted samples. Also, the same oxygen vacancy induced disorder could explain the reduction in the fraction of the sample showing antiferromagnetic order. We also report significant changes in the measured properties of the samples as a function of time.