Fabrication and superconductivity of NaxTaS2 crystals

TL;DR

This study reports the growth of NaxTaS2 crystals, their superconducting properties, and how sodium intercalation influences the suppression of charge density waves and enhances superconductivity.

Contribution

It provides new insights into how sodium intercalation affects the structure, superconductivity, and charge density wave behavior in NaxTaS2 crystals.

Findings

Superconducting transition temperature (Tc) increases with sodium content.

Charge density wave (CDW) is suppressed with higher sodium intercalation.

Higher sodium content correlates with reduced anisotropy in resistivity.

Abstract

In this paper we report the growth and superconductivity of $Na_xTaS_2$ crystals. The structural data deduced from X-ray diffraction pattern shows that the sample has the same structure as $2H-TaS_2$. A series of crystals with different superconducting transition temperatures ($T_c$) ranging from 2.5 K to 4.4 K were obtained. It is found that the $T_c$ rises with the increase of $Na$ content determined by Energy-Dispersive x-ray microanalysis(EDX) of Scanning Electron Microscope (SEM) on these crystals. Compared with the resistivity curve of un-intercalated sample $2H-TaS_2$ ($T_c$ = 0.8 K, $T_{CDW} \approx$ 70 K), no signal of charge density wave (CDW) was observed in samples $Na_{0.1}TaS_2$ and $Na_{0.05}TaS_2$. However, in some samples with lower $T_c$, the CDW appears again at about 65 K. Comparison between the anisotropic resistivity indicates that the anisotropy becomes smaller in samples with more $Na$ intercalation (albeit a weak semiconducting behavior along c-axis) and thus higher $T_c$. It is thus concluded that there is a competition between the superconductivity and the CDW. With the increase of sodium content, the rise of $T_c$ in $Na_xTaS_2$ is caused mainly by the suppression to the CDW in $2H-TaS_2$, and the conventional rigid band model for layered dichalcogenide may be inadequate to explain the changes induced by the slight intercalation of sodium in $2H-TaS_2$.