Twist of cholesteric liquid crystal cells: stability of helical structures and anchoring energy effects

TL;DR

This paper analyzes the stability of helical structures in cholesteric liquid crystal cells, focusing on how anchoring energy and asymmetry influence transitions between different twist configurations.

Contribution

It provides a detailed stability analysis of cholesteric liquid crystal helical structures, including effects of anchoring energy asymmetry on transition mechanisms.

Findings

In-plane director fluctuations can dominate transition mechanisms.

Asymmetry introduces instability gaps between stable configurations.

Large anchoring asymmetry suppresses jump-like twist transitions.

Abstract

We consider helical configurations of a cholesteric liquid crystal (CLC) sandwiched between two substrates with homogeneous director orientation favored at both confining plates. We study the CLC twist wavenumber $q$ characterizing the helical structures in relation to the free twisting number $q_0$ which determines the equilibrium value of CLC pitch, $P_0=2\pi/q_0$. We investigate the instability mechanism underlying transitions between helical structures with different spiral half-turn numbers. Stability analysis shows that for equal finite anchoring strengths this mechanism can be dominated by in-plane director fluctuations. In this case the metastable helical configurations are separated by the energy barriers and the transitions can be described as the director slippage through these barriers. We extend our analysis to the case of an asymmetric CLC cell in which the anchoring strengths at the two substrates are different. The asymmetry introduces two qualitatively novel effects: (a) the intervals of twist wavenumbers representing locally stable configurations with adjacent helix half-turn numbers are now separated by the instability gaps; and (b) sufficiently large asymmetry, when the difference between azimuthal anchoring extrapolation lengths exceeds the thickness of the cell, will suppress the jump-like behaviour of the twist wavenumber.