High pressure high temperature (HPHT) synthesis and magnetization of Magneto-Superconducting RuSr2(LnCe2)Cu2O12.25 (Ru-1232) compounds (Ln = Y and Dy)

TL;DR

This study reports the successful synthesis of Ru-1232 compounds with Y and Dy, exhibiting magnetic transitions and superconductivity, and compares their properties with related ruthenocuprate systems.

Contribution

First successful synthesis of near single-phase Ru-1232 compounds with Y and Dy, revealing magnetic and superconducting properties and their relation to structural parameters.

Findings

Magnetic transition at ~90 K with hysteresis loops up to Tmag.

Superconducting transition at ~30 K.

Magnetic ordering temperature scales with RuO6 octahedra distance.

Abstract

RuSr2(LnCe2)Cu2O12.25 (Ru-1232) compounds with Ln = Y and Dy being synthesized by high pressure high temperature (6GPa, 12000C) solid state synthesis route do crystallize in space group P4/mmm in near single phase form with small quantities of SrRuO3 and RuSr2(RE1.5Ce0.5)Cu2O10 (Ru-1222). Both samples exhibit magnetic transitions (Tmag.) at ~90 K with significant branching of zfc (zero-field-cooled) and fc (field-cooled) magnetization and a sharp cusp in zfc at ~ 70 K, followed by superconducting transitions at ~ 30 K. Both compounds show typical ferromagnetic hysteresis loops in magnetic moment (M) versus field (H) magnetization right upto Tmag. i.e. < 90K. To our knowledge these are the first successfully synthesized Ru-1232 compounds in near single phase with lanthanides including Y and Dy. The results are compared with widely reported Gd/Ru-1222 and Ru-1212 (RuSr2GdCu2O8) compounds. In particular, it seems that the Ru moments magnetic ordering temperature (Tmag.) scales with the c-direction distance between magnetic RuO6 octahedras in Ru-1212/1222 or 1232 systems.