Landau-Zener problem for energies close to potential crossing points
V.A.Benderskii, E.V.Vetoshkin (Institute of Problems of Chemical, Physics, Moscow Region, Chernogolovka, Russia), E. I. Kats (Laue-Langevin, Institute, Grenoble, France, and L. D. Landau Institute for Theoretical, Physics, RAS, Moscow, Russia)

TL;DR
This paper investigates the Landau-Zener problem near potential crossing points, calculating a 4x4 connection matrix that accounts for all coupled states in the intermediate energy region, extending previous models.
Contribution
It introduces a comprehensive 4x4 connection matrix for the Landau-Zener problem near crossing points, addressing a previously overlooked energy region.
Findings
Derived the 4x4 connection matrix for intermediate energies
Matched the matrix with known solutions in tunneling and over-barrier regions
Enhanced understanding of state coupling near crossing points
Abstract
We examine one overlooked in previous investigations aspect of well - known Landau - Zener (LZ) problem, namely, the behavior in the intermediate, i.e. close to a crossing point, energy region, when all four LZ states are coupled and should be taken into account. We calculate the 4 x 4 connection matrix in this intermediate energy region, possessing the same block structure as the known connection matrices for the tunneling and in the over-barrier regions of the energy, and continously matching those in the corresponding energy regions.
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