Magnetic and Transport Properties in $CoSr_2Y_{1-x}Ca_xCu_2O_7$ ($x$=0$\sim$0.4)

TL;DR

This study investigates how calcium doping affects the magnetic and electrical properties of $CoSr_2Y_{1-x}Ca_xCu_2O_7$, revealing a close relationship between magnetic behavior and charge transport involving $CoO_{1+ ext{delta}}$ layers.

Contribution

It provides new insights into the role of $CoO_{1+ ext{delta}}$ layers in charge transport and magnetic properties in calcium-doped cobalt cuprate systems.

Findings

Calcium doping reduces resistivity significantly.

Magnetic properties change notably with higher Ca levels.

Charge transfer occurs into $CoO_{1+ ext{delta}}$ layers, affecting magnetism and transport.

Abstract

Magnetic and transport properties of $Co Sr_2 Y_{1-x} Ca_x Cu_2 O_7$ ($x=0 \sim 0.4$) system have been investigated. A broad maximum in M(T) curve, indicative of low-dimensional antiferromagnetic ordering originated from $CoO_{1+\delta}$ layers, is observed in Ca-free sample. With increasing Ca doping level up to 0.2, the M(T) curve remains almost unchanged, while resistivity is reduced by three orders. Higher Ca doping level leads to a drastic change of magnetic properties. In comparison with the samples with $x=0.0 \sim 0.2$, the temperature corresponding to the maximum of M(T) is much lowered for the sample $x$=0.3. The sample $x$=0.4 shows a small kink instead of a broad maximum and a weak ferromagnetic feature. The electrical transport behavior is found to be closely related to magnetic properties for the sample $x$=0.2, 0.25, 0.3, 0.4. It suggests that $CoO_{1+\delta}$ layers are involved in charge transport in addition to conducting $CuO_2$ planes to interpret the correlation between magnetism and charge transport. X-ray photoelectron spectroscopy studies give an additional evidence of the the transfer of the holes into the $CoO_{1+\delta}$ charge reservoir.