Absence of ferromagnetism in Mn- and Co-doped ZnO

TL;DR

This study conclusively shows that Mn- and Co-doped ZnO samples do not exhibit ferromagnetism, contradicting some previous reports, and suggests they are unlikely suitable for spintronics without additional carriers.

Contribution

The paper provides experimental evidence that Mn- and Co-doped ZnO do not show ferromagnetism under specific conditions, challenging earlier claims and clarifying their magnetic properties.

Findings

All doped samples show Curie-Weiss behavior.

No ferromagnetism observed at 2% and 6% doping levels.

Samples are not suitable for spintronics without additional carriers.

Abstract

Following the theoretical predictions of ferromagnetism in Mn- and Co-doped ZnO, several workers reported ferromagnetism in thin films as well as in bulk samples of these materials. While some observe room-temperature ferromagnetism, others find magnetization at low temperatures. Some of the reports, however, cast considerable doubt on the magnetism of Mn- and Co-doped ZnO. In order to conclusively establish the properties of Mn- and Co-doped ZnO, samples with 6 percent and 2 percent dopant concentrations, have been prepared by the low-temperature decomposition of acetate solid solutions. The samples have been characterized by x-ray diffraction, EDAX and spectroscopic methods to ensure that the dopants are substitutional. All the Mn- and Co-doped ZnO samples (prepared at 400 deg C and 500 deg C) fail to show ferromagnetism. Instead, their magnetic properties are best described by a Curie-Weiss type behavior. It appears unlikely that these materials would be useful for spintronics, unless additional carriers are introduced by some means.