Topology and phase transitions: from an exactly solvable model to a relation between topology and thermodynamics

TL;DR

This paper provides new evidence linking topology changes in configuration space to phase transitions in an exactly solvable mean-field model, revealing a one-to-one correspondence and a novel mathematical characterization of first order transitions.

Contribution

It introduces a new mathematical framework connecting topology and thermodynamics, including a reduced configuration space and a functional relation involving Morse indexes.

Findings

Topology changes correspond to phase transitions in the model.

A one-to-one relation between topology and phase transitions is established.

A new characterization of first order transitions is proposed.

Abstract

The elsewhere surmised topological origin of phase transitions is given here new important evidence through the analytic study of an exactly solvable model for which both topology and thermodynamics are worked out. The model is a mean-field one with a k-body interaction. It undergoes a second order phase transition for k=2 and a first order one for k>2. This opens a completely new perspective for the understanding of the deep origin of first and second order phase transitions, respectively. In particular, a remarkable theoretical result consists of a new mathematical characterization of first order transitions. Moreover, we show that a "reduced" configuration space can be defined in terms of collective variables, such that the correspondence between phase transitions and topology changes becomes one-to-one, for this model. Finally, an unusual relationship is worked out between the microscopic description of a classical N-body system and its macroscopic thermodynamic behaviour. This consists of a functional dependence of thermodynamic entropy upon the Morse indexes of the critical points (saddles) of the constant energy hypersurfaces of the microscopic 2N-dimensional phase space. Thus phase space (and configuration space) topology is directly related to thermodynamics.